N‐Thiocyanato‐2,10‐camphorsultam Derivatives: Design and Applications of Original Electrophilic Thiocyanating Reagents - ANR - Agence nationale de la recherche Accéder directement au contenu
Article Dans Une Revue European Journal of Organic Chemistry Année : 2021

N‐Thiocyanato‐2,10‐camphorsultam Derivatives: Design and Applications of Original Electrophilic Thiocyanating Reagents

Résumé

The synthesis of bench-stable electrophilic thiocyanating reagents was depicted in two steps from readily available starting materials in good yields. These newly-designed electrophilic reagents were successfully applied for the thiocyanation of different nucleophiles under mild and transition metal-free conditions. Preliminary experiments for the asymmetric C3-thiocyanation of an oxindole derivative were also conducted leading to the expected product with no induction of chirality, although opening possibilities for accessing chiral compounds.
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Dates et versions

hal-03744635 , version 1 (16-11-2022)

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Citer

Mélissa Gao, Martin Vuagnat, Philippe Jubault, Tatiana Besset. N‐Thiocyanato‐2,10‐camphorsultam Derivatives: Design and Applications of Original Electrophilic Thiocyanating Reagents. European Journal of Organic Chemistry, 2021, 2022 (1), pp.e202101255. ⟨10.1002/ejoc.202101255⟩. ⟨hal-03744635⟩
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