Effect of home cooking processes on chlordecone content in beef and investigation of its by-products and metabolites by HPLC-HRMS/MS - ANR - Agence nationale de la recherche Accéder directement au contenu
Article Dans Une Revue Environment International Année : 2020

Effect of home cooking processes on chlordecone content in beef and investigation of its by-products and metabolites by HPLC-HRMS/MS

Effet des procédés de cuisson à domicile sur la teneur en chlordécone de la viande bovine et étude de ses sous-produits et métabolites par HPLC-HRMS/MS

Résumé

Chlordecone (CLD) is a toxic organochlorine pesticide frequently used in the French West Indies until 1993, resulting in a contamination of soil and food. This study assessed the behaviour of CLD residues and CLD processing factors (PFs) during four home cooking processes: cooking in a conventional oven ("oven"), frying ("pan"), cooking in a microwave oven ("microwave") and grilling ("grill"). These four processes were applied to six types of naturally contaminated beef (kidney, liver, rib, chuck, top-sirloin and sirloin). Targeted analyses with isotopic dilution were carried out by ID-HPLC-MS/MS to determine CLD concentrations before and after each cooking process and the corresponding processing factors. HPLC-HRMS/MS was used to find potential organochlorine degradation by-products and/or CLD metabolites present in samples by target, suspect and non-target screening. Cooking processes and especially microwave cooking led to a significant decrease in the CLD contained in beef (2% < PF < 17%). Traces of 5b-hydro-CLD and of another mono-hydro-CLD were found in the uncooked liver but no CLD degradation by-product was observed in the cooked liver.
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Dates et versions

hal-03158198 , version 1 (30-06-2021)

Identifiants

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Deborah Martin, Fiona Lobo, Gwenaëlle Lavison-Bompard, Thierry Guérin, Julien Parinet. Effect of home cooking processes on chlordecone content in beef and investigation of its by-products and metabolites by HPLC-HRMS/MS. Environment International, 2020, 144, pp.106077. ⟨10.1016/j.envint.2020.106077⟩. ⟨hal-03158198⟩

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