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Article Dans Une Revue Analyst Année : 2016

High performance optical oxygen sensors based on iridium complexes exhibiting interchromophore energy shuttling

Résumé

A doubly pyrene-grafted bis-cyclometallated iridium complex with engineered electronically excited states demonstrates reversible electronic energy transfer between adjacent chromophores giving rise to extremely long-lived red luminescence in solution (τ = 480 μs). Time-resolved spectroscopic studies afforded determination of pertinent photophysical parameters including rates of energy transfer and energy distribution between constituent chromophores in the equilibrated excited molecule (ca. 98% on the organic chromophores). Incorporation into a nanostructured metal–oxide matrix (AP200/19) gave highly sensitive O 2 sensing films, as the detection sensitivity was 200–300% higher than with the commonly used PtTFPP and approaches the sensitivity of the best O 2-sensing dyes reported to date.
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hal-01349284 , version 1 (27-07-2016)

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Santiago Medina-Rodríguez, Sergey A. Denisov, Yanouk Cudré, Louise Male, Marta Marín-Suárez, et al.. High performance optical oxygen sensors based on iridium complexes exhibiting interchromophore energy shuttling. Analyst, 2016, 141 (10), pp.3090-3097. ⟨10.1039/c6an00497k⟩. ⟨hal-01349284⟩
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